Hedge decompositions of tangential vector fields defined on piecewise regular manifolds are provided. The first step is the study of L-2 tangential fields and then the attention is focused on some particular Sobolev spaces of order - 1/2. In order to reach this goal, it is required to properly define the first order differential operators and to investigate their properties. When the manifold Gamma is the boundary of a polyhedron Omega, these spaces are important in the analysis of tangential trace mappings for vector fields in H(curl, Omega) on the whole boundary or on a part of it. By means of,these Hedge decompositions, one can then provide a complete characterization of these trace mappings: general extension theorems, from the boundary, or from a part of it, to the inside; definition of suitable dualities and validity of integration by parts formulae. Copyright (C) 2001 John Wiley & Sons, Ltd.