We show that for every c.e. degree a > 0 there exists an intrinsically c.e. relation on the domain of a computable structure whose degree spectrum is {0, a}. This result can be extended in two directions. First we show that for every uniformly c.e. collection of sets S there exists an intrinsically c.e. relation on the domain of a computable structure whose degree spectrum is the set of degrees of elements of S. Then we show that if $\alpha \in \omega\cup\{\omega \}$ then for any $\alpha$-c.e. degree a > 0 there exists an intrinsically $\alpha$-c.e. relation on the domain of a computable structure whose degree spectrum is {0, a}. All of these results also hold for m-degree spectra of relations.