The natural quotient map q from the space of based loops in the Hawaiian earring onto the fundamental group provides a naturally occuring example of a quotient map such that q × q fails to be a quotient map. With the quotient topology, this example shows π₁(X,p) can fail to be a topological group if X is locally path connected.
@article{bwmeta1.element.bwnjournal-article-doi-10_4064-ba59-1-9, author = {Paul Fabel}, title = {Multiplication is Discontinuous in the Hawaiian Earring Group (with the Quotient Topology)}, journal = {Bulletin of the Polish Academy of Sciences. Mathematics}, volume = {59}, year = {2011}, pages = {77-83}, zbl = {1229.54046}, language = {en}, url = {http://dml.mathdoc.fr/item/bwmeta1.element.bwnjournal-article-doi-10_4064-ba59-1-9} }
Paul Fabel. Multiplication is Discontinuous in the Hawaiian Earring Group (with the Quotient Topology). Bulletin of the Polish Academy of Sciences. Mathematics, Tome 59 (2011) pp. 77-83. http://gdmltest.u-ga.fr/item/bwmeta1.element.bwnjournal-article-doi-10_4064-ba59-1-9/