A Time-Dependent Born-Oppenheimer Approximation with Exponentially Small Error Estimates
Hagedorn, George A. ; Joye, Alain
arXiv, 0005006 / Harvested from arXiv
We present the construction of an exponentially accurate time-dependent Born-Oppenheimer approximation for molecular quantum mechanics. We study molecular systems whose electron masses are held fixed and whose nuclear masses are proportional to $\epsilon^{-4}$, where $\epsilon$ is a small expansion parameter. By optimal truncation of an asymptotic expansion, we construct approximate solutions to the time-dependent Schr\"odinger equation that agree with exact normalized solutions up to errors whose norms are bounded by $\ds C \exp(-\gamma/\epsilon^2)$, for some C and $\gamma>0$.
Publié le : 2000-05-03
Classification:  Mathematical Physics,  81Q20
@article{0005006,
     author = {Hagedorn, George A. and Joye, Alain},
     title = {A Time-Dependent Born-Oppenheimer Approximation with Exponentially Small
  Error Estimates},
     journal = {arXiv},
     volume = {2000},
     number = {0},
     year = {2000},
     language = {en},
     url = {http://dml.mathdoc.fr/item/0005006}
}
Hagedorn, George A.; Joye, Alain. A Time-Dependent Born-Oppenheimer Approximation with Exponentially Small
  Error Estimates. arXiv, Tome 2000 (2000) no. 0, . http://gdmltest.u-ga.fr/item/0005006/